The metabolism of methyl carbamate
نویسندگان
چکیده
منابع مشابه
Methyl N-(dimethoxyphosphoryl)carbamate
In the title compound, CH3OC(O)NHP(O)(OCH3)2, the P atom has a slightly distorted tetra-hedral configuration. The mixed imide moiety can be described as cisoid-transoid in which the two opposing dipoles (P=O and C=O) are oriented with a O=C⋯P=O torsion angle of 150.88(18)°. In the crystal, molecules are linked by pairs of N-H⋯O hydrogen bonds, forming inversion dimers.
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In the title mol-ecule, C(8)H(8)N(2)O(4), the nitro and meth-oxy-carbonyl groups are twisted from the plane of aromatic ring by 5.1 (1) and 6.2 (1)°, respectively. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules related by translation along the b axis into chains. Weak inter-molecular C-H⋯O inter-actions link further these chains into sheets parallel to the bc plane.
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There are three independent mol-ecules in the asymmetric unit of the title compound, C(9)H(11)NO(3), which are connected by O-H⋯O hydrogen bonds, forming an R(3) (3)(15) ring. The dihedral angles between the planes of the benzene and amide groups are 75.16 (3), 71.47 (3) and 70.56 (3)°. The hy-droxy O atom lies 0.912 (3), 1.172 (2) and 1.339 (2) Å from the mean plane of the corresponding benzen...
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ژورنال
عنوان ژورنال: Biochemical Journal
سال: 1952
ISSN: 0306-3283
DOI: 10.1042/bj0520267